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Synthesis of glycerol carbonate from glycerol and dimethyl carbonate in basic ionic liquids *
| Content Provider | Semantic Scholar |
|---|---|
| Author | Chiappe, Cinzia Rajamani, Sunita |
| Copyright Year | 2012 |
| Abstract | Glycerol carbonate is a key multifunctional compound used as solvent, additive, and building block in alternative chlorine-free processes. Here, we report the synthesis of glycerol carbonate from renewable materials (glycerol and dimethyl carbonate, DMC) using basic ionic liquids (ILs) as catalysts. After process optimization, it has been possible to isolate pure glycerol carbonate in quantitative yield using a three-fold excess of DMC and ca. 15 % of IL. The IL could be reused at least four times without any significant reduction in the conversion yield. |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | https://www.iupac.org/publications/pac/pdf/2012/pdf/8403x0755.pdf |
| Language | English |
| Access Restriction | Open |
| Subject Keyword | Calcium Carbonate 750 MG Chewable Tablet Calcium Carbonate 800 MG / Famotidine 10 MG / Magnesium Hydroxide 165 MG Chewable Tablet Carbonates Chlorine Circa Glycerin Ionic Liquids Liquid substance Mathematical optimization Multi-function printer Offset binary Process optimization Utility functions on indivisible goods methyl carbonate |
| Content Type | Text |
| Resource Type | Article |
