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Alkyl substituted poly(p-phenylene vinylene)s by ring opening metathesis polymerisation
| Content Provider | Semantic Scholar |
|---|---|
| Author | Lidster, Benjamin John Kumar, D. B. Rohini Spring, Andrew Mark Yu, Chin Yang Turner, Michael L. |
| Copyright Year | 2016 |
| Abstract | The ring opening metathesis polymerisation (ROMP) of three n-octyl substituted [2.2]paracyclophane-1,9-dienes, initiated by Grubbs ruthenium carbene complexes is reported. The molecular weight of the resulting alkyl-substituted poly(p-phenylene vinylene)s is determined by the monomer to initiator ratio and the polymers are isolated with relatively narrow polydispersities and control of the end groups. Only the pseudo-geminal isomer of the tetra-alkyl substituted [2.2]paracyclophane-1,9-diene was susceptible to ROMP. The optical properties of the two series of polymers was investigated. |
| Starting Page | 5544 |
| Ending Page | 5551 |
| Page Count | 8 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C6PY01186A |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/c6/py/c6py01186a/c6py01186a1.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C6PY01186A |
| Volume Number | 7 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
