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Bis[μ-1,4-bis(4,5-dihydro-1H-imidazol-2-yl)benzene-κ2 N 3:N 3′]silver(I) dinitrate dihydrate
| Content Provider | Semantic Scholar |
|---|---|
| Author | Sun, Hua Ren, Chun-Xia Shen, Bin Liu, Zhi-qiang Ding, Yu-qiang |
| Copyright Year | 2008 |
| Abstract | The reaction of 1,4-bis-(4,5-dihydro-1H-imidazol-2-yl)benzene (bib) with silver(I) nitrate in a 1:1 molar ratio generates the metallacyclic title complex, [Ag(2)(C(12)H(14)N(4))(2)](NO(3))(2)·2H(2)O, in which the bib ligand displays a cis configuration. Each bib ligand acts as a bidentate bridging ligand connecting a pair of Ag(I) ions to form a [2 + 2] metallamacrocycle in which the Ag⋯Ag distance is 6.77 (2) Å. Each Ag(I) ion has weak contacts (2.91 Å) with the nitrate anion. The uncoordinated water mol-ecules make hydrogen bonds with nitrate O atoms, forming chains. The H atoms attached to the uncoordinated nitro-gen inter-act with these chains through N-H⋯O hydrogen bonds, forming layers parallel to the (11) plane. |
| Starting Page | m427 |
| Ending Page | m428 |
| Page Count | 1 |
| File Format | PDF HTM / HTML |
| PubMed reference number | 21201371v1 |
| DOI | 10.1107/s1600536808001633 |
| Journal | Acta crystallographica. Section E, Structure reports online |
| Volume Number | 64 |
| Alternate Webpage(s) | http://ftp.ncbi.nlm.nih.gov/pub/pmc/da/21/e-64-0m427.PMC2960425.pdf |
| Alternate Webpage(s) | https://doi.org/10.1107/S1600536808001633 |
| Language | English |
| Access Restriction | Open |
| Subject Keyword | Anions Bibs GEN1 wt Allele Ions Isosorbide Dinitrate Ligands Molar Ratio Mole, unit of measurement Nitrates anatomical layer |
| Content Type | Text |
| Resource Type | Article |
