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Chirality detection of two enantiomorphic 3D lanthanide coordination polymers by vibrational circular dichroism spectra.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Zheng, Xiu-Ying Zhang, Han Cao, Ling-Yun Kong, Xiang-Jian Long, Lasheng Zheng, Lan-Sun |
| Copyright Year | 2015 |
| Abstract | Two enantiomorphic 3D lanthanide coordination polymers of {[Dy5(L)4(H2O)10][Dy(H2O)7][Na(H2O)5]}·(ClO4)7·(H2O)15 (1a for R and 1b for S) with chiral helical chains were synthesized based on an achiral ligand N-(2-hydroxyethyl)ethylenediamine-N,N',N'-triacetic acid (H3L) and Dy(ClO4)3. Crystal analysis revealed that 1a and 1b were crystallized in chiral space groups P4132 and P4332, respectively. The absolute configurations of the two structures were evidenced by vibrational circular dichroism (VCD) spectra with one single crystal sample. |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/c5dt00404g |
| PubMed reference number | 25710701 |
| Journal | Medline |
| Volume Number | 44 |
| Issue Number | 12 |
| Alternate Webpage(s) | http://pubs.rsc.org/en/Content/ArticlePDF/2015/DT/C5DT00404G |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/c5/dt/c5dt00404g/c5dt00404g1.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/c5dt00404g |
| Journal | Dalton transactions |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
