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Controlled synthesis and Li-electroactivity of rutile TiO2 nanostructure with walnut-like morphology.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Kim, Dong Hoe Min, Kyung-Mi Park, Kyung-Soo Park, Ik Jae Seong, Won Mo Kim, Dong-Wan |
| Copyright Year | 2013 |
| Abstract | Herein, we report on the synthesis of phase-pure rutile walnut-like TiO(2) (W-TiO(2)) spheres composed of single-crystalline nanorod-building blocks using a surfactant-free non-aqueous acidic modified "benzyl alcohol route". Based on the various HCl concentration- and reaction time-dependent experiments, an effect of hydrochloric acid on the phase formation mechanism in a non-aqueous system is suggested. As anodes for Li-ion batteries, the W-TiO(2) sphere electrodes exhibited superior cycling performance at a rate of 0.2 C without any conducting layers coated onto the anodes; this result is attributed to their high crystallinity and large surface area. |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/c2dt32251j |
| PubMed reference number | 23340880 |
| Journal | Medline |
| Volume Number | 42 |
| Issue Number | 12 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/dt/c2/c2dt32251j/c2dt32251j.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/c2dt32251j |
| Journal | Dalton transactions |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |