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Organoboron star polymersvia arm-first RAFT polymerization: synthesis, luminescent behavior, and aqueous self-assembly
| Content Provider | Semantic Scholar |
|---|---|
| Author | Cheng, Fei Bonder, Edward M. Doshi, Ami Jäkle, Frieder |
| Copyright Year | 2012 |
| Abstract | The first examples of organoboron star polymers were prepared by arm-first RAFT polymerization using a novel luminescent organoboron crosslinker in combination with PS, PNIPAM, P4VP, and PNIPAM-b-PS as linear polymer precursors. Well-defined star architectures with a luminescent core were successfully obtained as confirmed by GPC-MALLS, NMR, DLS, and TEM analysis. The PNIPAM-b-PS stars are amphiphilic and undergo self-assembly in water with formation of super-aggregates that exhibit strong green fluorescence. The P4VP stars lend themselves to further functionalization at the periphery. |
| Starting Page | 596 |
| Ending Page | 600 |
| Page Count | 5 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C2PY00556E |
| Volume Number | 3 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/py/c2/c2py00556e/c2py00556e.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C2PY00556E |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
