NDLI: Two cadmium(II) coordination polymers constructed by carboxylate and pyridine mixed ligands: synthesis, structure and luminescent properties

Content Provider	Semantic Scholar
Author	Zhang, Xiao-Xiao Zhou, Jing-Min Zhang, Zhenjie Cheng, Peng
Copyright Year	2013
Abstract	Two new cadmium(II) coordination polymers (CPs), {[Cd(BTG)(bpy)(H2O)]·0.5glycol·H2O}n (1) and {[Cd6(BTB)4(bpy)4.5(glycol)]·9H2O}n (2) (H2BTG = 1,2,3-benzene tricarboxylic acid 2-(2-hydroxy-ethyl) ester, an ester of 1,2,3-benzenetricarboxylic acid and glycol; H3BTB = 1,2,3-benzenetricarboxylic acid), have been synthesized with the same reactants but different reaction conditions. CP 1 possesses an interesting stair-shaped 2D (4,4) network that stacks in a parallel fashion with a dihedral angle of 80.599(5)°. CP 2 exhibits a complicated 3D structure which can be simplified into a 3,10-connected network with an unreported Schlafli symbol of {32·4}{34·421·513·67}. The luminescent properties of CPs 1 and 2 are studied.
Starting Page	9738
Ending Page	9744
Page Count	7
File Format	PDF HTM / HTML
DOI	10.1039/C3CE41073K
Alternate Webpage(s)	http://www.rsc.org/suppdata/ce/c3/c3ce41073k/c3ce41073k.pdf
Alternate Webpage(s)	https://doi.org/10.1039/C3CE41073K
Volume Number	15
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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