Charge transfer spectra of square planar d(8) transition metal complexes.

Content Provider	Semantic Scholar
Author	Batiste, John L. H.
Copyright Year	1970
Abstract	E l e c t r o n i c s p e c t r a o f some a n i o n s (C l , Br , I , SCN , a n d CN ) a n d o f s e v e r a l c o m p l e x e s o f t h e t y p e [ M X , (m = P d ( l l ) , P t ( l l ) ; X = C l , CN ) w e r e r e c o r d e d i n w a t e r a n d d e u t e r i u m o x i d e t o a l o w e r w a v e l e n g t h l i m i t o f 170 m,u. I m p r o v e d r e s o l u t i o n was o b t a i n e d v i a t h e u s e o f s h o r t p a t h l e n g t h c e l l s . C o m p le x e s o f t h e t y p e [MX^] (M = P d ( l l ) , P t ( l l ) , A u ( l l l ) ; X = C l , Br , CN ) w e r e a l s o e x a m i n e d t o t h e 170 mp, l i m i t i n a c e t o n i t r i l e . A t r i a l a n d e r r o r G a u s s i a n a n a l y s i s o f t h e s p e c t r a was a i d e d by a low t e m p e r a t u r e (168°K) t h i n f i l m t e c h n i q u e . T r e n d s i n t h e h i g h f r e q u e n c y b a n d s a r e d i s c u s s e d . The h a l i d e c o m p l e x e s show l i g a n d -* m e t a l c h a r g e t r a n s f e r b a n d s a n d m e t a l -• l i g a n d c h a r g e t r a n s f e r b a n d s a t e v e n h i g h e r e n e r g y . T he c y a n i d e c o m p l e x e s e x h i b i t b o t h d d a n d m e t a l -* l i g a n d c h a r g e t r a n s f e r b a n d s . Th e e l e c t r o n i c s p e c t r u m o f P t f e n l C l g was e x a m i n e d i n w a t e r a n d d e u t e r i u m o x i d e .
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Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article