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Thermodynamics of Complexation of Cytidine 5'- monophosphate (CMP) with Mn (II), Co(II), Ni(II) Cu(II) and Zn(II) ions in Aqueous Media
| Content Provider | Semantic Scholar |
|---|---|
| Author | Singh, Mukul Kumar |
| Copyright Year | 2011 |
| Abstract | Crow's mean diffusion coefficient method applied to diffusion currents in the polarographic study of complexation of Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) with cytidine 5'- monophoshate yielded the logK 1 and logK 2 values as Mn(II) 2.76, 1.76; Co(II) 2.37, 1.46, Ni(II) 2.86, 0.843; Cu(II) 3.06, 1.90 and Zn(II) 3.93, 2.01 at 293 K. The overall stability constants followed Irving-William natural order. Thermodynamic parameters ∆G, ∆H and ∆S values calculated in the range 293-303 K were all negative, proving the formation of strong complexes with greater order in their molecule. |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | http://www.orientjchem.org/download/26070/ |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
