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Oxidation of organic compounds by phenyl iodoso acetate (II). Kinetics and mechanism of oxidation of aldo-sugars
| Content Provider | Semantic Scholar |
|---|---|
| Author | Pati, Subas C. Mahapatro, R. C. |
| Copyright Year | 1979 |
| Abstract | Kinetics of oxidation of five aldo-sugars by phenyl iodoso acetate in aqueous acetic acid medium in presence of perchloric acid has been investigated. The reaction has first order dependence on both substrate and oxidant. The reaction is retarded by perchloric acid and has unit inverse dependence on acidity. Increase in acetic acid in the solvent composition decreases the rate. A suitable mechanism involving the complex formation between the oxidant and substrate is postulated which explains the observed kinetic data. |
| Starting Page | 203 |
| Ending Page | 210 |
| Page Count | 8 |
| File Format | PDF HTM / HTML |
| DOI | 10.1007/BF02844803 |
| Volume Number | 88 |
| Alternate Webpage(s) | https://page-one.springer.com/pdf/preview/10.1007/BF02844803 |
| Alternate Webpage(s) | https://doi.org/10.1007/BF02844803 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |