Ruthenium Phosphine/Diimine Complexes: Syntheses, Characterization, Reactivity with Carbon Monoxide, and Catalytic Hydrogenation of Ketones †

Content Provider	Semantic Scholar
Author	Araujo, Márcio P. De Figueiredo, Alberthmeiry T. De Bogado, André L. Poelhsitz, Gustavo Von Ellena,, Javier Castellano, Eduardo E. Donnici, Claudio L. Comasseto, João Valdir Batista, Alzir Azevedo
Copyright Year	2005
Abstract	The cis-[RuCl2(PPh3)2(N−N)] (N−N = bipy (1), Me-bipy (2), phen (3), and bathophen (4)) complexes were used to synthesize five new electron-rich phosphine-containing complexes cis-[RuCl2(dcype)(N−N)] (N−N = bipy (1a), Me-bipy (2a), phen (3a), and bathophen (4a)) and cis-[RuCl2(PEt3)2(bipy)] (1c) by phosphine exchange. These complexes were obtained and characterized by NMR (31P{1H}, 1H), cyclic voltammetry, and elemental analysis. Electrochemical studies of these complexes reveal a single reduction process (RuIII/RuII). These complexes are more easily oxidized than their analogues cis-[RuCl2(dppb)(N−N)]. The reactivity of complexes cis-[RuCl2(dcype)(N−N)] with carbon monoxide was tested, and dissociation of one chloride was observed, leading to the formation of four new cationic species with general formula [RuCl(CO)(dcype)(N−N)](PF6) (bipy (1b), Me-bipy (2b), phen (3b), and bathophen (4b)). The complexes described here and elsewhere with general formulas cis-[RuCl2(P−P)(N−N)], [RuCl(CO)(dcype)(N−N)](PF6), ...
Starting Page	6159
Ending Page	6168
Page Count	10
File Format	PDF HTM / HTML
DOI	10.1021/om050182b
Volume Number	24
Alternate Webpage(s)	http://www.cmdmc.com.br/redecmdmc/lab/arquivos_publicacoes/89_Ruthenium%20Phosphine%20Diimine%20Complexes%20%20Syntheses.pdf
Alternate Webpage(s)	https://doi.org/10.1021/om050182b
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article