NDLI: Hydrogen bonding in the perhydrate and hydrates of 1,4-diazabicyclo[2.2.2]octane (DABCO)

Content Provider	Semantic Scholar
Author	Laus, Gerhard Kahlenberg, Volker Wurst, Klaus Loerting, Thomas Schottenberger, Herwig
Copyright Year	2008
Abstract	The crystal structures of the bis(perhydrate), the monohydrate, and the hexahydrate of 1,4-diazabicyclo[2.2.2]octane (DABCO) were determined by single-crystal X-ray diffraction to investigate the hydrogen bonding architectures. The bis(perhydrate) revealed helical chains of hydrogen peroxide molecules forming a 3-D network by interaction with the diamine. In the monohydrate, water and diamine molecules are alternately linked. In the hexahydrate, cyclic water aggregates create cavities which are occupied by DABCO molecules doubly hydrogen-bonded to the water framework of the cage.
Starting Page	1638
Ending Page	1644
Page Count	7
File Format	PDF HTM / HTML
DOI	10.1039/B807303A
Volume Number	10
Alternate Webpage(s)	https://www.uibk.ac.at/physchem/staff_folder/tloerting/publications/laus08-cec.pdf
Alternate Webpage(s)	http://www.rsc.org/suppdata/ce/b8/b807303a/b807303a.pdf
Alternate Webpage(s)	https://doi.org/10.1039/B807303A
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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