NDLI: A second polymorph with composition Co3(PO4)2·H2O

Please wait, while we are loading the content...

A second polymorph with composition Co3(PO4)2·H2O

Content Provider	Semantic Scholar
Author	Lee, Young Hoon Clegg, Jack K. Lindoy, Leonard F. Park, Yu-Chul Kim, Yang Hee
Copyright Year	2008
Abstract	Single crystals of Co(3)(PO(4))(2)·H(2)O, tricobalt(II) bis-[ortho-phosphate(V)] monohydrate, were obtained under hydro-thermal conditions. The compound is the second polymorph of this composition and is isotypic with its zinc analogue, Zn(3)(PO(4))(2)·H(2)O. Three independent Co(2+) cations are bridged by two independent orthophosphate anions. Two of the metal cations exhibit a distorted tetra-hedral coordination while the third exhibits a considerably distorted [5 + 1] octa-hedral coordination environment with one very long Co-O distance of 2.416 (3) Å. The former cations are bonded to four different phosphate anions, and the latter cation is bonded to four anions (one of which is bidentate) and one water mol-ecule, leading to a framework structure. Additional hydrogen bonds of the type O-H⋯O stabilize this arrangement.
Starting Page	i69
Ending Page	i70
Page Count	2
File Format	PDF HTM / HTML
DOI	10.1107/S1600536808028365
PubMed reference number	21200979
Journal	Medline
Volume Number	64
Alternate Webpage(s)	http://journals.iucr.org/e/issues/2008/10/00/wm2194/wm2194.pdf
Alternate Webpage(s)	https://doi.org/10.1107/S1600536808028365
Journal	Acta crystallographica. Section E, Structure reports online
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in