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Ab initio structure determination of [Eu5(C2H4O2)6(CH3CO2)3]n by X‐ray powder diffraction
| Content Provider | Semantic Scholar |
|---|---|
| Author | Abdallah, Amal Ammar, Souad Ban, Voraksmy Sibille, Romain François, Michel |
| Copyright Year | 2018 |
| Abstract | The compound [Eu5(C2H4O2)6(CH3CO2)3]n was synthesized by dissolving acetate europium salt in ethylene glycol solvent and heating under reflux for a short time. Its structure was solved ab initio from synchrotron powder diffraction data using optimization methods in direct space. The compound has a very large unit-cell volume of 23679 A3 and the highest centred cubic symmetry space group, Ia{\bar 3}d (No. 230). The porous metal–organic framework structure is similar to those usually observed in zeolites, with pores volumes of 82 A3, which is of potential interest for gas storage. |
| Starting Page | 592 |
| Ending Page | 597 |
| Page Count | 6 |
| File Format | PDF HTM / HTML |
| DOI | 10.1107/S2052520618012982 |
| Alternate Webpage(s) | http://journals.iucr.org/b/issues/2018/06/00/ra5042/ra5042.pdf |
| Alternate Webpage(s) | https://doi.org/10.1107/S2052520618012982 |
| Volume Number | 74 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |