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Photoredox-catalyzed stereoselective alkylation of enamides with N-hydroxyphthalimide esters via decarboxylative cross-coupling reactions† †Electronic supplementary information (ESI) available. CCDC 1874601. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c9sc030
| Content Provider | Semantic Scholar |
|---|---|
| Author | Guo, Jing-Yu Zhang, Zeyu Guan, Ting Mao, Lei-Wen Ban, Qian Zhao, Kai Loh, Teck-Peng |
| Copyright Year | 2019 |
| Abstract | Stereoselective b-C(sp)–H alkylation of enamides with redox-active N-hydroxyphthalimide esters via a photoredox-catalyzed decarboxylative cross-coupling reaction is demonstrated. This methodology features operational simplicity, broad substrate scopes, and excellent stereoselectivities and functional group tolerance, affording a diverse array of geometrically defined and synthetically valuable enamides bearing primary, secondary or tertiary alkyl groups in satisfactory yields. |
| Starting Page | 8792 |
| Ending Page | 8798 |
| Page Count | 7 |
| File Format | PDF HTM / HTML |
| PubMed reference number | 31803451 |
| Volume Number | 10 |
| Alternate Webpage(s) | https://pubs.rsc.org/en/content/articlepdf/2019/sc/c9sc03070k |
| Journal | Chemical Science |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |