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Solvent-free isomerization of allylic alcohols catalyzed by a rhodium catalyst-organic framework
| Content Provider | Semantic Scholar |
|---|---|
| Author | Corkum, Elizabeth G. Kalapugama, Suneth Hass, Michael J. Bergens, Steven H. |
| Copyright Year | 2012 |
| Abstract | The solvent-free isomerization of allylic alcohols is reported using an immobilized rhodium catalyst-organic framework (COF) synthesized from alternating ring-opening metathesis polymerization (altROMP) assembly. The catalyst provided TONs as high as 38 000, with catalyst loadings as low as 0.0025 mol% for the isomerizations. Kinetic resolution of starting allylic alcohol 5 was also observed. |
| Starting Page | 3473 |
| Ending Page | 3476 |
| Page Count | 4 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C2RA20197F |
| Volume Number | 2 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/ra/c2/c2ra20197f/c2ra20197f.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C2RA20197F |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |