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Migratory insertion of [B(C6F5)2] into C-H bonds: CO promoted transfer of the boryl fragment.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Aldridge, Simon Kays, Deborah L. Al-Fawaz, Amal Jones, Kevin Mark Horton, Peter N. Hursthouse, Michael B. Harrington, Ross W. Clegg, William |
| Copyright Year | 2006 |
| Abstract | The reaction of (eta(5)-C5H5)Fe(CO)2B(C6F5)2 with CO has been shown to proceed via ligand substitution at the metal with accompanying transfer of the boryl fragment (via C-H insertion) to the Cp ring, thereby generating the zwitterion [eta(5)-C5H4B(C6F5)2H]Fe(CO)3 in quantitative yield. |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/b604141h |
| PubMed reference number | 16779483 |
| Journal | Medline |
| Volume Number | 24 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/cc/b6/b604141h/b604141h.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/b604141h |
| Journal | Chemical communications |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |