Determination of chloride ion diffusion coefficients for zinc dissolution in a low temperature molten salt

Content Provider	Semantic Scholar
Author	Simonsen, Leif R. Donahue, Francis Michael
Copyright Year	1990
Abstract	Abstract The transport properties and stoichiometry of the zinc dissolution process in mixtures of aluminum chloride and 1-methyl-3-ethylimidazolium chloride were studied. A new mass transfer correlation for rotating cylinder electrodes was found for these high Schmidt number electrolytes. Two limiting current regions were observed during the dissolution process which corresponded to a coordination number of four at low overpotentials and a coordination number of three at high overpotentials. The quantity D μ/ T was calculated to be 3.5 × 10 −10 , which corresponds to a chloride ion radius of 2.1 × 10 −8 cm.
Starting Page	89
Ending Page	92
Page Count	4
File Format	PDF HTM / HTML
DOI	10.1016/0013-4686(90)85042-L
Volume Number	35
Alternate Webpage(s)	https://deepblue.lib.umich.edu/bitstream/handle/2027.42/28798/0000632.pdf;jsessionid=F2DD9EB7269625748FA504D0BEC57969?sequence=1
Alternate Webpage(s)	https://doi.org/10.1016/0013-4686%2890%2985042-L
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article