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Different routes to methanol: inelastic neutron scattering spectroscopy of adsorbates on supported copper catalysts.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Kandemir, Timur Friedrich, Matthias G. Parker, Stewart F. Studt, Felix Lennon, David Schlögl, Robert Behrens, Malte |
| Copyright Year | 2016 |
| Abstract | We have investigated methanol synthesis with model supported copper catalysts, Cu/ZnO and Cu/MgO, using CO/H2 and CO2/H2 as feedstocks. Under CO/H2 both catalysts show chemisorbed methoxy as a stable intermediate, the Cu/MgO catalyst also shows hydroxyls on the support. Under CO2/H2 the catalysts behave differently, in that formate is also seen on the catalyst. For the Cu/ZnO catalyst hydroxyls are present on the metal whereas for the Cu/MgO hydroxyls are found on the support. These results are consistent with a recently published model for methanol synthesis and highlight the key role of ZnO in the process. |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/c6cp00967k |
| Alternate Webpage(s) | http://eprints.gla.ac.uk/118610/1/118610.pdf |
| Alternate Webpage(s) | https://pubs.rsc.org/en/content/articlepdf/2016/cp/c6cp00967k?page=search |
| Alternate Webpage(s) | https://pure.mpg.de/rest/items/item_2305417_8/component/file_2321193/content |
| PubMed reference number | 27075638 |
| Alternate Webpage(s) | https://doi.org/10.1039/c6cp00967k |
| Journal | Medline |
| Volume Number | 18 |
| Issue Number | 26 |
| Journal | Physical chemistry chemical physics : PCCP |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
