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A new anionic metal–organic framework showing tunable emission by lanthanide(III) doping and highly selective CO2 adsorption properties
| Content Provider | Semantic Scholar |
|---|---|
| Author | Chen, Rong-Ying Tian, Dan Bi Li, Yunwu Lv, Yingbin Sun, Hong-Wei Chang, Ze Bu, Xian-He |
| Copyright Year | 2015 |
| Abstract | A new three-dimensional porous metal–organic framework, {[NH2(CH3)2][Zn(atz)(ox)]·H2O}n (1) (Hatz = 5-amino-1H-tetrazole, H2ox = oxalic acid), has been solvothermally synthesized and characterized by elemental analysis, IR, TG, and single-crystal X-ray diffraction analysis. Complex 1 exhibits an anionic framework that can be simplified as a rarely reported 4-connected lon network. Complex 1 could be utilized as a platform for emission tuning by doping different lanthanide ions. In addition, gas adsorption studies reveal that 1 has a high isosteric heat of CO2 and good adsorption selectivity for CO2 over CH4 and N2. |
| Starting Page | 24655 |
| Ending Page | 24660 |
| Page Count | 6 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C5RA02935J |
| Volume Number | 5 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/c5/ra/c5ra02935j/c5ra02935j1.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C5RA02935J |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
