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Palladium–catalyzed synthesis of 2,3-dihydro-2-substituted-2-vinyl-1,4-benzodioxins
| Content Provider | Semantic Scholar |
|---|---|
| Author | Labrosse, Jean– Robert Pichon, Nathalie Goux-Henry, Catherine Lhoste, Paul Sinou, Denis |
| Copyright Year | 2002 |
| Abstract | Various 2,3-dihydro-2-substituted-2-vinyl-1,4-benzodioxins 6 are obtained by alkylation of the methyl carbonate of 2,3-dihydro-1,4-benzodioxin-2-ylideneethanol 5 with various carbon nucleophiles in the presence of a palladium complex. Altough the yields in alkytion products are good in the case of a non-bulky nucleophile, formation of the diene 7 was generally observed when a bulky nucleophile was used. |
| File Format | PDF HTM / HTML |
| DOI | 10.3998/ark.5550190.0003.512 |
| Volume Number | 2002 |
| Alternate Webpage(s) | https://quod.lib.umich.edu/cgi/p/pod/dod-idx/palladium-catalyzed-synthesis-of-23-dihydro-2-substituted-2.pdf?c=ark&format=pdf&idno=5550190.0003.512 |
| Alternate Webpage(s) | https://doi.org/10.3998/ark.5550190.0003.512 |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |
