NDLI: Mechanistic insight into the hydroxylation of alkanes by a nonheme iron(V)-oxo complex.

Content Provider	Semantic Scholar
Author	Kwon, Eunji Cho, Kyung-Bin Seungwoo Nam, Wonwoo
Copyright Year	2014
Abstract	Hydroxylation of alkanes by a mononuclear nonheme iron(V)-oxo complex, [Fe(V)(O)(TAML)](-), is initiated by a rate-determining hydrogen atom (H-atom) abstraction, followed by an oxygen non-rebound process. Evidence for the H-atom abstraction-oxygen non-rebound mechanism is obtained experimentally and supported by DFT calculations.
File Format	PDF HTM / HTML
DOI	10.1039/c4cc01058b
PubMed reference number	24722791
Journal	Medline
Volume Number	50
Issue Number	42
Alternate Webpage(s)	http://www.rsc.org/suppdata/cc/c4/c4cc01058b/c4cc01058b1.pdf
Alternate Webpage(s)	http://cbs.ewha.ac.kr/pub/data/2014_11_ChemComm_50(42)_5572_5575.pdf
Alternate Webpage(s)	https://doi.org/10.1039/c4cc01058b
Journal	Chemical communications
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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