NDLI: The selective hydrogenation of furfural over supported palladium nanoparticle catalysts prepared by sol-immobilisation: effect of catalyst support and reaction conditions

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The selective hydrogenation of furfural over supported palladium nanoparticle catalysts prepared by sol-immobilisation: effect of catalyst support and reaction conditions

Content Provider	Semantic Scholar
Author	Albilali, Reem Douthwaite, Mark He, Qian Taylor, Stuart
Copyright Year	2018
Abstract	The selective hydrogenation of bio-derived furfural was investigated under mild conditions using a series of supported palladium catalysts prepared by a sol-immobilisation technique. Catalysts using alumina and titania supports were more selective towards tetrahydrofurfuryl alcohol. The catalytic activity of 1.19% Pd/TiO2 was evaluated under different reaction conditions and higher selectivity towards tetrahydrofurfuryl alcohol was observed when using 2-propanol as a solvent, and the yield of tetrahydrofurfuryl alcohol decreased as reaction temperature increased. The performance of the Pd catalyst was enhanced by the addition of Pt and a 95% yield of tetrahydrofurfuryl alcohol was achieved. The catalysts were characterised using a range of techniques, and the synergistic effect of adding Pt to Pd was due to an electronic promotional effect.
Starting Page	252
Ending Page	267
Page Count	16
File Format	PDF HTM / HTML
DOI	10.1039/C7CY02110K
Alternate Webpage(s)	http://orca-mwe.cf.ac.uk/106659/1/Catal%20Sci%20Technol%20final%20clean%20furfural%20manuscript%2014%20Oct%202017.pdf
Alternate Webpage(s)	https://doi.org/10.1039/C7CY02110K
Volume Number	8
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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