NDLI: A Rh(II)-catalyzed cycloaddition approach towards the synthesis of komaroviquinone.

Content Provider	Semantic Scholar
Author	Padwa, Albert Chughtai, Majid J. Boonsombat, Jutatip Rashatasakhon, Paitoon
Copyright Year	2008
Abstract	Using a rhodium(II)-catalyzed cyclization/cycloaddition sequence as the key reaction step, the icetexane core of komaroviquinone was constructed by an intramolecular dipolar-cycloaddition of a carbonyl ylide dipole across a tethered pi-bond. The ylide was arrived at by cyclization of a rhodium carbenoid intermediate onto a proximal ester group. Efforts towards the preparation of the required precursor for elaboration to the natural product are discussed.
Starting Page	4758
Ending Page	4767
Page Count	10
File Format	PDF HTM / HTML
DOI	10.1016/j.tet.2008.01.129
PubMed reference number	19461991
Journal	Medline
Volume Number	64
Issue Number	21
Alternate Webpage(s)	https://open.library.emory.edu/publications/emory:txg6z/pdf/
Alternate Webpage(s)	https://doi.org/10.1016/j.tet.2008.01.129
Journal	Tetrahedron
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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A Rh(II)-catalyzed cycloaddition approach towards the synthesis of komaroviquinone.