NDLI: Highly selective synthesis of catalytically active monodisperse rhodium nanocubes.

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Highly selective synthesis of catalytically active monodisperse rhodium nanocubes.

Content Provider	Semantic Scholar
Author	Zhang, Yawen Grass, Michael E. Kuhn, John N. Tao, Feng Habas, Susan Ellen Huang, Wenyu Yang, Peidong Somorjai, Gabor A.
Copyright Year	2008
Abstract	Monodisperse sub-10 nm Rh nanocubes were synthesized with high selectivity (>85%) by a seedless polyol method. The {100} faces of the Rh NCs were effectively stabilized by chemically adsorbed Br- ions from trimethyl(tetradecyl)ammonium bromide (TTAB). This simple one-step polyol route can be readily applied to the preparation of Pt and Pd nanocubes. Moreover, the organic molecules of PVP and TTAB that encapsulated the Rh nanocubes did not prevent catalytic activity for pyrrole hydrogenation and CO oxidation.
Starting Page	183
Ending Page	188
Page Count	6
File Format	PDF HTM / HTML
Alternate Webpage(s)	https://cloudfront.escholarship.org/dist/prd/content/qt7pf4g8dj/qt7pf4g8dj.pdf?t=li5s14
Alternate Webpage(s)	https://works.bepress.com/wenyu_huang/23/download/
Alternate Webpage(s)	http://nanowires.berkeley.edu/wp-content/uploads/2013/01/162.pdf
Alternate Webpage(s)	http://nanowires.berkeley.edu/wp-content/uploads/2013/01/162_SI.pdf
Alternate Webpage(s)	http://www.cchem.berkeley.edu/pdygrp/pub_files/pubpdf/162_SI.pdf
PubMed reference number	18399628v1
Alternate Webpage(s)	https://doi.org/10.1021/ja801210s
DOI	10.1021/ja801210s
Journal	Journal of the American Chemical Society
Volume Number	130
Issue Number	18
Language	English
Access Restriction	Open
Subject Keyword	Bromides Carbon Monoxide Face Hydrogenation Ions Palladium Povidone Pyrroles Rh:Type:Pt:Bld:Nom Rhodium enzyme activity methscopolamine bromide oxidation polyol
Content Type	Text
Resource Type	Article

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