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Boryl substituted group 13 metallylenes: complexes with an iron carbonyl fragment.
| Content Provider | Semantic Scholar |
|---|---|
| Author | Sindlinger, Christian Patrick Aldridge, Simon Jones, Cameron |
| Copyright Year | 2016 |
| Abstract | The first examples of boryl substituted aluminylene and gallylene complexes, [(DAB)B(THF)Al{Fe(CO)3(μ-CO)}]2 and [(DAB)BGa{μ-Fe(CO)4}]2 (DAB = {(C6H3Pri2-2,6)NCH}2) have been prepared by reduction of MX2(THF){B(DAB)} (M = Al or Ga, X = Cl or Br) with K2[Fe(CO)4]. Spectroscopic and crystallographic analyses of the compounds show them to be structurally distinct dimers, the latter of which possesses a close GaGa separation that computational analyses reveal has negligible bonding character. |
| Starting Page | 149 |
| Ending Page | 152 |
| Page Count | 4 |
| File Format | PDF HTM / HTML |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/c6/cc/c6cc08449d/c6cc08449d1.pdf |
| PubMed reference number | 27824166v1 |
| Volume Number | 53 |
| Issue Number | 1 |
| Journal | Chemical communications |
| Language | English |
| Access Restriction | Open |
| Subject Keyword | Bromides Iron Carbonyl Limanda limanda Pyschological Bonding |
| Content Type | Text |
| Resource Type | Article |
