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Mechanistic studies of the copolymerization between ethyl diazoacetate and cinnamaldehyde
| Content Provider | Semantic Scholar |
|---|---|
| Author | Chen, Cheng Li, Feifei Liao, Liqiong Liu, Lijian |
| Copyright Year | 2017 |
| Abstract | The Ndiazo,C3-diradical of diazomethane (˙NN–H2C˙) is a resonance structure with 1,3-dipole form. And alkyl diazoacetate (ethyl diazoacetate, EDA) can interact with α,β-unsaturated aldehyde (cinnamaldehyde, CA) without any catalyst to compose the Ndiazo,C5- and Ndiazo,C8-diradicals, which are the building species to produce the copolymer of EDA with CA through a sequential series of Ndiazo,Cω-diradical intermediates. |
| Starting Page | 2881 |
| Ending Page | 2888 |
| Page Count | 8 |
| File Format | PDF HTM / HTML |
| DOI | 10.1039/C6PY02126C |
| Volume Number | 8 |
| Alternate Webpage(s) | http://www.rsc.org/suppdata/c6/py/c6py02126c/c6py02126c1.pdf |
| Alternate Webpage(s) | https://doi.org/10.1039/C6PY02126C |
| Language | English |
| Access Restriction | Open |
| Content Type | Text |
| Resource Type | Article |