NDLI: Stabilization of BH4 Group in Zinc Borohydride via Adduct of Ammonia towards a Pure Hydrogen Release

Content Provider	Semantic Scholar
Author	Gao, Liang Guo, Yanhui Wallwork, Kia S. Zhang, Feiwu Yu, Xuebin
Copyright Year	2013
Abstract	mixture of ZnCl2·2NH3/2LiBH4. Structure analysis shows that the subsequent complex has a monoclinic structure with unit-cell parameters of a = 6.392(4) Å, b = 8.417(6) Å, c = 6.388(4) Å and β = 92.407(4) ° and space group P21, in which Zn atoms coordinate with two BH4 groups and two NH3 groups. The interatomic distances reported herein show that Zn-H bonding in Zn(BH4)2·2NH3 is shorter than Ca-H bonds in Ca(BH4)2·2NH3 and Mg-H in Mg(BH4)2·2NH3. This reduced bond contact leads to an increase 10
File Format	PDF HTM / HTML
Alternate Webpage(s)	https://espace.curtin.edu.au/bitstream/handle/20.500.11937/43259/187457_187457.pdf?isAllowed=y&sequence=2
Language	English
Access Restriction	Open
Content Type	Text
Resource Type	Article

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