NDLI: Iron‐Catalyzed Borrowing Hydrogen C ‐Alkylation of Oxindoles with Alcohols

Content Provider	Scilit
Author	Dambatta, Mubarak B. Polidano, Kurt Northey, Alexander D. Williams, Jonathan M. J. Morrill, Louis Christian
Copyright Year	2019
Description	Journal: ChemSusChem A general and efficient iron‐catalyzed C‐alkylation of oxindoles has been developed. This borrowing hydrogen approach employs a (cyclopentadienone)iron carbonyl complex (2 mol %) and exhibits a broad reaction scope, allowing benzylic and simple primary and secondary aliphatic alcohols to be employed as alkylating agents. A variety of oxindoles undergo selective mono‐C(3)‐alkylation in good to excellent isolated yields (28 examples, 50‐92% yield, 79% average yield).
Related Links	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6619250/pdf
Ending Page	2349
Page Count	5
Starting Page	2345
e-ISSN	1864564X
DOI	10.1002/cssc.201900799
Journal	ChemSusChem
Issue Number	11
Volume Number	12
Language	English
Publisher	Wiley-Blackwell
Publisher Date	2019-04-08
Access Restriction	Open
Subject Keyword	Journal: ChemSusChem Organic Chemistry Iron Catalysis Borrowing Hydrogen
Content Type	Text
Resource Type	Article

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Iron‐Catalyzed Borrowing Hydrogen C ‐Alkylation of Oxindoles with Alcohols