NDLI: Parallels between Metal‐Ligand Cooperativity and Frustrated Lewis Pairs

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Parallels between Metal‐Ligand Cooperativity and Frustrated Lewis Pairs

Content Provider	Scilit
Author	Habraken, Evi R. M. Jupp, Andrew R. Brands, Maria B. Nieger, Martin Ehlers, Andreas W. Slootweg, J. Chris
Copyright Year	2019
Description	Journal: European Journal of Inorganic Chemistry Metal ligand cooperativity (MLC) and frustrated Lewis pair (FLP) chemistry both feature the cooperative action of a Lewis acidic and a Lewis basic site. A lot of work has been carried out in the field of FLPs to prevent Lewis adduct formation, which often reduces the FLP reactivity. Parallels are drawn between the two systems by looking at their reactivity with CO2, and we explore the role of steric bulk in preventing dimer formation in MLC systems.
Related Links	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6687039/pdf
Ending Page	2442
Page Count	7
Starting Page	2436
ISSN	14341948
e-ISSN	10990682
DOI	10.1002/ejic.201900169
Journal	European Journal of Inorganic Chemistry
Issue Number	19
Volume Number	2019
Language	English
Publisher	Wiley-Blackwell
Publisher Date	2019-04-17
Access Restriction	Open
Subject Keyword	Journal: European Journal of Inorganic Chemistry Inorganic Chemistry Lewis Acid Lewis Base Frustrated Lewis Pairs Metal Ligand Cooperativity Dft Calculations
Content Type	Text
Resource Type	Article
Subject	Inorganic Chemistry

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