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Concerted Nucleophilic Aromatic Substitution Reactions
| Content Provider | Scilit |
|---|---|
| Author | Rohrbach, Simon Smith, Andrew J. Pang, Jia Hao Poole, Darren L. Tuttle, Tell Chiba, Shunsuke Murphy, John A. |
| Copyright Year | 2019 |
| Description | Journal: Angewandte Chemie International Edition Recent developments in experimental and computational chemistry have identified a rapidly growing class of nucleophilic aromatic substitutions that proceed by concerted (cSNAr),1,2 rather than classical two‐step, SNAr mechanisms. Whereas traditional SNAr reactions require substantial activation of the aromatic ring by electron‐withdrawing substituents, such activating groups are not mandatory in the concerted pathways. At this crucial stage of growth in understanding of these reactions, our aim is to review the current state of knowledge on CSNAr reactions. [The review includes many types of substrates and nucleophiles; it specifically excludes transition metal‐related processes that might involve concerted substitutions on arenes]. |
| Related Links | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6899550/pdf |
| Ending Page | 16388 |
| Page Count | 21 |
| Starting Page | 16368 |
| ISSN | 14337851 |
| e-ISSN | 15213773 |
| DOI | 10.1002/anie.201902216 |
| Journal | Angewandte Chemie International Edition |
| Issue Number | 46 |
| Volume Number | 58 |
| Language | English |
| Publisher | Wiley-Blackwell |
| Publisher Date | 2019-04-16 |
| Access Restriction | Open |
| Subject Keyword | Journal: Angewandte Chemie International Edition Organic Chemistry Concerted Reactions Csnar Mechanism Meisenheimer Complex Nucleophilic Aromatic Substitution |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Catalysis |
