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Total Synthesis of (+)-Rubriflordilactone A
| Content Provider | Scilit |
|---|---|
| Author | Goh, Shermin S. Chaubet, Guilhem Gockel, Birgit Cordonnier, Marie-Caroline A. Baars, Hannah Phillips, Andrew W. Anderson, Edward A. |
| Copyright Year | 2015 |
| Description | Journal: Angewandte Chemie International Edition Two enantioselective total syntheses of the nortriterpenoid natural product rubriflordilactone A are described, which use palladium- or cobalt-catalyzed cyclizations to form the CDE rings, and converge on a late-stage synthetic intermediate. These key processes are set up through the convergent coupling of a common diyne component with appropriate AB-ring aldehydes, a strategy that sets the stage for the synthetic exploration of other members of this family of natural products. |
| Related Links | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4643188/pdf |
| Ending Page | 12621 |
| Page Count | 4 |
| Starting Page | 12618 |
| ISSN | 14337851 |
| e-ISSN | 15213773 |
| DOI | 10.1002/anie.201506366 |
| Journal | Angewandte Chemie International Edition |
| Issue Number | 43 |
| Volume Number | 54 |
| Language | English |
| Publisher | Wiley-Blackwell |
| Publisher Date | 2015-09-04 |
| Access Restriction | Open |
| Subject Keyword | Journal: Angewandte Chemie International Edition Organic Chemistry Cyclotrimerization Transition Metal Catalysis |
| Content Type | Text |
| Resource Type | Article |
| Subject | Chemistry Catalysis |
