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Silver(I) Complexes of Two Flexible Bis‐phospholane Ligands: Metallamacrocycles, Polymeric Chains, and Metallacryptands
| Content Provider | Scilit |
|---|---|
| Author | Boar, Paul Lönnecke, Peter Hey‐Hawkins, Evamarie |
| Copyright Year | 2020 |
| Description | Journal: Zeitschrift für anorganische und allgemeine Chemie In a 2:2 reaction with silver(I) chloride or bromide, 1,5‐bis(1‐phospholano)pentane (1a) afforded frame‐like macrocyclic structures, with intra‐ (2, Cl) or intermolecular (3, Br) halido bridges. In contrast, 1,7‐bis(1‐phospholano)heptane (1b) formed coordination polymers 4a (Cl) and 4b (Br) with bridging bis‐phospholane and halido ligands. A unique paddle wheel‐type metallacryptand structure 5 was obtained from 1a and silver(I) bromide in a 2:3 reaction (M:L). All complexes were fully characterized by NMR, IR spectroscopy, mass spectrometry, and X‐ray crystallography. |
| Related Links | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7386914/pdf |
| Ending Page | 922 |
| Page Count | 8 |
| Starting Page | 915 |
| e-ISSN | 15213749 |
| DOI | 10.1002/zaac.202000001 |
| Journal | Zeitschrift für anorganische und allgemeine Chemie |
| Issue Number | 13 |
| Volume Number | 646 |
| Language | English |
| Publisher | Wiley-Blackwell |
| Publisher Date | 2020-05-12 |
| Access Restriction | Open |
| Subject Keyword | Journal: Zeitschrift für anorganische und allgemeine Chemie Inorganic Chemistry Metallamacrocycles Structure Elucidation |
| Content Type | Text |
| Resource Type | Article |
