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The application of the Diels-Alder reaction to polymer syntheses based on furan/maleimide reversible couplings
| Content Provider | Scilit |
|---|---|
| Author | Gandini, Alessandro |
| Copyright Year | 2005 |
| Description | The furan heterocycle is a dienic reagent particularly suitable for the Diels-Alder reaction and maleimides represent a typical family of complementary reagents because of their strong dienophilic character. This paper reviews critically the studies devoted to the exploitation of the Diels Alder reaction between those moieties to synthesise macromolecular materials possessing different structures and properties. The most relevant approaches in this field are (i) polycondensation reactions calling upon A-A and B-B monomers and (ii) reversible cross-linking of linear polymers bearing pendant furan or maleimide moieties, based on the temperature sensitivity of the Diels-Alder equilibrium |
| Related Links | http://www.scielo.br/scielo.php?script=sci_pdf&pid=S0104-14282005000200007&lng=en&nrm=iso&tlng=en |
| ISSN | 01041428 |
| e-ISSN | 16785169 |
| DOI | 10.1590/s0104-14282005000200007 |
| Journal | Polímeros |
| Issue Number | 2 |
| Volume Number | 15 |
| Language | English |
| Publisher | FapUNIFESP (SciELO) |
| Publisher Date | 2005-06-01 |
| Access Restriction | Open |
| Subject Keyword | Polímeros Polymer Science Reaction To Polymer Reversible Couplings Syntheses Based Polymer Syntheses maleimide Reversible Diels Alder Alder Reaction |
| Content Type | Text |
| Resource Type | Article |
| Subject | Organic Chemistry Chemical Engineering |