NDLI: Using hydrazine to link ferrocene with Re(CO)3: A modular approach

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Using hydrazine to link ferrocene with Re(CO)3: A modular approach

Content Provider	Scilit
Author	Chanawanno, Kullapa Rhoda, Hannah M. Hasheminasab, Abed Crandall, Laura A. King, Alexander J. Herrick, Richard S. Nemykin, Victor N. Ziegler, Christopher J.
Copyright Year	2016
Description	Journal: Journal of Organometallic Chemistry Acetyl ferrocene and diacetyl ferrocene both readily react with an excess of hydrazine to afford the corresponding hydrazone compounds. These compounds can then be linked to Re(CO) via a metal-mediated Schiff base reaction, resulting in a series of ferrocene-Re(CO) conjugates with different stoichiometries. Conjugates with 1:1, 1:2, and 2:1 ferrocene: Re(CO) ratios can be produced via this "modular" type synthesis approach. Several examples of these conjugates were structurally characterized, and their spectroscopic, electrochemical, and spectroelectrochemical behaviors were investigated. The electronic structures of these compounds were also probed using DFT and TDDFT calculations.
Related Links	http://europepmc.org/articles/pmc5421566?pdf=render https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5421566/pdf
Ending Page	153
Page Count	9
Starting Page	145
ISSN	0022328X
DOI	10.1016/j.jorganchem.2016.06.004
Journal	Journal of Organometallic Chemistry
Volume Number	818
Language	English
Publisher	Elsevier BV
Publisher Date	2016-09-01
Access Restriction	Open
Subject Keyword	Journal: Journal of Organometallic Chemistry Inorganic Chemistry Schiff Base Conjugate Density Functional Theory Tricarbonyl Rhenium(i)
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry Materials Chemistry Biochemistry Physical and Theoretical Chemistry Inorganic Chemistry

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