NDLI: Determination of Pd(II) using an antimony film coated on a screen-printed electrode by adsorptive stripping voltammetry

Please wait, while we are loading the content...

Determination of Pd(II) using an antimony film coated on a screen-printed electrode by adsorptive stripping voltammetry

Content Provider	Scilit
Author	Pérez-Ràfols, Clara Trechera, Pedro Serrano, Núria Díaz-Cruz, José Manuel Ariño, Cristina Esteban, Miquel
Copyright Year	2017
Description	Journal: Talanta The use of an antimony film coated on a screen-printed carbon electrode (ex-situ SbSPCE) is proposed for the determination of Pd(II) at ppb levels in natural samples by adsorptive stripping voltammetry using dimethylglyoxime as chelating agent. Ex-situ SbSPCE produces a better analytical performance as compared to a commercially sputtered bismuth screen-printed electrode (BiSPE). The detection and quantification limits were 2.7 and 9.0µgL respectively with a good linear behaviour in the wide examined concentration range (from 1µgL up to 100.0µgL, R=0.998). The proposed ex-situ SbSPCE showed an excellent repeatability with a relative standard deviation of 0.5% for ten successive measurements and a very good reproducibility (1.6% for three different ex-situ SbSPCE units within series of ten repetitive assays). Moreover, the ex-situ SbSPCE was successfully applied for the determination of low concentration levels of Pd(II) in spiked tap water with a very high reproducibility (0.2%) and providing equivalent results to those achieved by ICP-MS measurements.
Related Links	http://diposit.ub.edu/dspace/bitstream/2445/125567/1/667361.pdf
Ending Page	7
Page Count	7
Starting Page	1
ISSN	00399140
DOI	10.1016/j.talanta.2017.01.084
Journal	Talanta
Volume Number	167
Language	English
Publisher	Elsevier BV
Publisher Date	2017-05-01
Access Restriction	Open
Subject Keyword	Analytical Chemistry Adsorptive Stripping Voltammetry Antimony Film Electrode Screen-printed Electrode
Content Type	Text
Resource Type	Article
Subject	Spectroscopy Analytical Chemistry Biochemistry

Sl.	Authority	Responsibilities	Communication Details
1	Ministry of Education (GoI), Department of Higher Education	Sanctioning Authority	https://www.education.gov.in/ict-initiatives
2	Indian Institute of Technology Kharagpur	Host Institute of the Project: The host institute of the project is responsible for providing infrastructure support and hosting the project	https://www.iitkgp.ac.in
3	National Digital Library of India Office, Indian Institute of Technology Kharagpur	The administrative and infrastructural headquarters of the project	Dr. B. Sutradhar bsutra@ndl.gov.in
4	Project PI / Joint PI	Principal Investigator and Joint Principal Investigators of the project	Dr. B. Sutradhar bsutra@ndl.gov.in Prof. Saswat Chakrabarti will be added soon
5	Website/Portal (Helpdesk)	Queries regarding NDLI and its services	support@ndl.gov.in
6	Contents and Copyright Issues	Queries related to content curation and copyright issues	content@ndl.gov.in
7	National Digital Library of India Club (NDLI Club)	Queries related to NDLI Club formation, support, user awareness program, seminar/symposium, collaboration, social media, promotion, and outreach	clubsupport@ndl.gov.in
8	Digital Preservation Centre (DPC)	Assistance with digitizing and archiving copyright-free printed books	dpc@ndl.gov.in
9	IDR Setup or Support	Queries related to establishment and support of Institutional Digital Repository (IDR) and IDR workshops	idr@ndl.gov.in