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Humidity effect on adsorption kinetics of ammonia onto electrospun SnO2 nanofibers
| Content Provider | Scilit |
|---|---|
| Author | Ömür, Birsel Can |
| Copyright Year | 2018 |
| Description | Journal: Materials Research Express Tin dioxide nanofibers were successfully synthesized by electrospinning homogeneous solution of SnCl4•5H2O in polyvinyl alcohol (PVA) and the potential of SnO2 nanofibers as ammonia sensing element at room temperature were also investigated. A logarithmic dependence of sensitivity on ammonia concentration was observed. We further investigate the effect of relative humidity between 0% and 70% on ammonia sensing performance of SnO2 nanofibers based conductometric sensor for the first time. Sensing experiments showed that both the baseline sensor current and the response-recovery characteristics of the SnO2 based sensor modified by pre humidification of sensing layer' surface. To study the adsorption kinetics pseudo first order and Elovich models was used and the first order kinetic model best describes the ammonia adsorption onto the SnO2 nanofibers for low concentrations ( 80 ppm) of ammonia, irrespective of humidity level. On the other hand, the results describe the best representation of Elovich model, as evidenced by the high correlation coefficients, for high concentrations of ammonia gas. |
| Related Links | http://iopscience.iop.org/article/10.1088/2053-1591/aafa27/pdf |
| ISSN | 20531591 |
| e-ISSN | 20531591 |
| DOI | 10.1088/2053-1591/aafa27 |
| Journal | Materials Research Express |
| Issue Number | 4 |
| Volume Number | 6 |
| Language | English |
| Publisher | IOP Publishing |
| Publisher Date | 2018-12-20 |
| Access Restriction | Open |
| Subject Keyword | Journal: Materials Research Express |
| Content Type | Text |
| Resource Type | Article |
| Subject | Surfaces, Coatings and Films Metals and Alloys Biomaterials Electronic, Optical and Magnetic Materials Polymers and Plastics |
