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Fabrication of CuO-doped catalytic material containing zeolite synthesized from red mud and rice husk ash for CO oxidation
| Content Provider | Scilit |
|---|---|
| Author | Thi, Minh Hieu Do Tran, Quoc Thinh Nguyen, Tri Thi, Thuy Van Nguyen Huynh, Ky Phuong Ha |
| Copyright Year | 2018 |
| Description | Journal: Advances in Natural Sciences: Nanoscience and Nanotechnology In this study a series of the CuO-doped materials containing zeolite with varying CuO contents were synthesized from red mud (RM) and rice husk ash (RHA). The rice husk ash/red mud with the molar ratio of , and being 1.8, 2.5 and 60, respectively, were maintained during the synthetic process of materials. The characteristic structure samples were analyzed by x-ray diffraction (XRD), Fourier transformed infrared spectroscopy (FTIR), scanning electron microscopy (SEM), transmission electron microscope (TEM), Brunauer–Emmett–Teller (BET) surface area and $H_{2}$ temperature program reduction $(H_{2}$-TPR). The catalytic activity of samples was evaluated in CO oxidation reaction in a microflow reactor at temperature range 200 °C–350 °C. The obtained results showed that all synthetic samples there exist the A-type zeolites with the average crystal size of 15–20 nm, the specific surface area of , and pore volume of . The material synthesized from RM and RHA with the zeolite structure (ZRM, undoped CuO) could also oxidize CO completely at 350 °C, and its activity was increase significantly when doped with CuO. CuO-doped materials with the zeolite structure exhibited excellent catalytic activity in CO oxidation. The ZRM sample loading 5 wt% CuO with particle nanosize about 10–30 nm was the best one for CO oxidation with complete conversion temperature at 275 °C. |
| Related Links | http://iopscience.iop.org/article/10.1088/2043-6254/aabe4e/pdf |
| ISSN | 20436254 |
| e-ISSN | 20436262 |
| DOI | 10.1088/2043-6254/aabe4e |
| Journal | Advances in Natural Sciences: Nanoscience and Nanotechnology |
| Issue Number | 2 |
| Volume Number | 9 |
| Language | English |
| Publisher | IOP Publishing |
| Publisher Date | 2018-06-01 |
| Access Restriction | Open |
| Subject Keyword | Journal: Advances in Natural Sciences: Nanoscience and Nanotechnology Chemical Engineering Cuo Doped Materials Co Oxidation |
| Content Type | Text |
| Resource Type | Article |