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Magnetic field aligned orderly arrangement of Fe$ _{3}$ O$ _{4}$ nanoparticles in CS/PVA/Fe$ _{3}$ O$ _{4}$ membranes
| Content Provider | Scilit |
|---|---|
| Author | Du, Meng Cao, Xing-Zhong Xia, Rui Zhou, Zhong-Po Jin, Shuo-Xue Wang, Bao-Yi |
| Copyright Year | 2018 |
| Description | Journal: Chinese Physics B The $CS/PVA/Fe_{3}O_{4}$ nanocomposite membranes with chainlike arrangement of $Fe_{3}O_{4}$ nanoparticles are prepared by a magnetic-field-assisted solution casting method. The aim of this work is to investigate the relationship between the microstructure of the magnetic anisotropic $CS/PVA/Fe_{3}O_{4}$ membrane and the evolved macroscopic physicochemical property. With the same doping content, the relative crystallinity of $CS/PVA/Fe_{3}O_{4}$-M is lower than that of $CS/PVA/Fe_{3}O_{4}$. The Fourier transform infrared spectroscopy (FT-TR) measurements indicate that there is no chemical bonding between polymer molecule and $Fe_{3}O_{4}$ nanoparticle. The $Fe_{3}O_{4}$ nanoparticles in $CS/PVA/Fe_{3}O_{4}$ and $CS/PVA/Fe_{3}O_{4}$-M are wrapped by the chains of CS/PVA, which is also confirmed by scanning electron microscopy (SEM) and x-ray diffraction (XRD) analysis. The saturation magnetization value of $CS/PVA/Fe_{3}O_{4}$-M obviously increases compared with that of non-magnetic aligned membrane, meanwhile the transmittance decreases in the UV-visible region. The o-Ps lifetime distribution provides information about the free-volume nanoholes present in the amorphous region. It is suggested that the microstructure of $CS/PVA/Fe_{3}O_{4}$ membrane can be modified in its curing process under a magnetic field, which could affect the magnetic properties and the transmittance of nanocomposite membrane. In brief, a full understanding of the relationship between the microstructure and the macroscopic property of $CS/PVA/Fe_{3}O_{4}$ nanocomposite plays a vital role in exploring and designing the novel multifunctional materials. |
| Related Links | http://iopscience.iop.org/article/10.1088/1674-1056/27/2/027805/pdf |
| ISSN | 16741056 |
| e-ISSN | 20583834 |
| DOI | 10.1088/1674-1056/27/2/027805 |
| Journal | Chinese Physics B |
| Issue Number | 2 |
| Volume Number | 27 |
| Language | English |
| Publisher | IOP Publishing |
| Publisher Date | 2018-02-01 |
| Access Restriction | Open |
| Subject Keyword | Journal: Chinese Physics B Condensed Matter Physics Relationship Between the Microstructure Nanocomposite Membranes |
| Content Type | Text |
| Resource Type | Article |
| Subject | Physics and Astronomy |