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A study of ionic transport properties on a new Ag+-ion-conducting composite electrolyte system: (1-x)[0.75Agl : 0.25AgCl] :xSiO2

Content Provider	Scilit
Author	Agrawal, R. C. Verma, Mohan L. Gupta, Ravindra Kumar
Copyright Year	1998
Description	Journal: Journal of Physics D: Applied Physics Preparation of a new -ion-conducting two-phase composite electrolyte system , (in molar weight fraction) and studies of its ionic transport properties are reported. Nano-size ( nm) particles of insulating and insoluble were used as second-phase dispersoid particles, while a new compound, `a quenched/annealed [] mixed-system/solid solution', recently investigated in the present laboratory, was used as the first-phase host matrix in place of the conventional host salt AgI. Various routes of sample preparation were adopted. The composition exhibited the highest enhancement in the room-temperature conductivity from that of the host. We referred to this as the `optimum conducting composition (OCC)' with room temperature conductivity about . The coexistence of constituent phases was confirmed by x-ray diffraction (XRD) and differential scanning calorimetry (DSC) studies. Various ionic transport parameters, namely the conductivity, mobility, mobile-ion concentration, transference number and drift velocity of the conducting ion, were measured experimentally as functions of the temperature. The results have been explained on the basis of theories proposed for two-phase composite electrolyte systems.
Related Links	http://iopscience.iop.org/article/10.1088/0022-3727/31/20/020/pdf
Ending Page	2860
Page Count	7
Starting Page	2854
ISSN	00223727
e-ISSN	13616463
DOI	10.1088/0022-3727/31/20/020
Journal	Journal of Physics D: Applied Physics
Issue Number	20
Volume Number	31
Language	English
Publisher	IOP Publishing
Publisher Date	1998-10-21
Access Restriction	Open
Subject Keyword	Journal: Journal of Physics D: Applied Physics X Ray Diffraction Sample Preparation Differential Scanning Calorimetry
Content Type	Text
Resource Type	Article
Subject	Surfaces, Coatings and Films Acoustics and Ultrasonics Condensed Matter Physics Electronic, Optical and Magnetic Materials

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