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The geometry of the Wannier two-electron ionisation ladder and the corresponding spectrum
| Content Provider | Scilit |
|---|---|
| Author | Nicolaides, C. A. Chrysos, M. Komninos, Y. |
| Copyright Year | 1988 |
| Description | Journal: Journal of Physics B: Atomic, Molecular and Optical Physics Numerical results of a variety of atoms, using the theory of those doubly excited states (DES) which define the two-electron ionisation ladder (TEIL), demonstrate that the degree of localisation on the Wannier ridge is already high for n>or=5. These results are used to interpret the behaviour of the TEIL as an effective rigid rotor system, whose energy spectrum is deduced to be E_{n}=An(n-1)/r^{2}$_{n}$, where A is a constant, characteristic of the system, and $r_{n}$ is the average value of the radii of the pair of valence electrons, calculated from first principles. The prediction is made that the TEIL states can be distinguished from the other DES in complex photoabsorption spectra according to the spectral characteristics of the rigid rotor in external static fields. |
| Related Links | http://iopscience.iop.org/article/10.1088/0953-4075/21/4/001/pdf |
| Ending Page | L76 |
| Page Count | 4 |
| Starting Page | L73 |
| ISSN | 09534075 |
| e-ISSN | 13616455 |
| DOI | 10.1088/0953-4075/21/4/001 |
| Journal | Journal of Physics B: Atomic, Molecular and Optical Physics |
| Issue Number | 4 |
| Volume Number | 21 |
| Language | English |
| Publisher | IOP Publishing |
| Publisher Date | 1988-02-28 |
| Access Restriction | Open |
| Subject Keyword | Journal: Journal of Physics B: Atomic, Molecular and Optical Physics Atomic, Molecular and Chemical Physics Electron Ionisation Ladder Two Electron Ionisation |
| Content Type | Text |
| Resource Type | Article |
| Subject | Atomic and Molecular Physics, and Optics Condensed Matter Physics |