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Quantitative analysis of titanium concentration using calibration-free laser-induced breakdown spectroscopy (LIBS)
| Content Provider | Scilit |
|---|---|
| Author | Zaitun Isnaeni Prasetyo, S. Suliyanti, M. M. Herbani, Y. |
| Copyright Year | 2018 |
| Description | Journal: Journal of Physics: Conference Series Laser-induced breakdown spectroscopy (LIBS) can be used for quantitative and qualitative analysis. Calibration-free LIBS (CF-LIBS) is a method to quantitatively analyze concentration of elements in a sample in local thermodynamic equilibrium conditions without using available matrix-matched calibration. In this study, we apply CF-LIBS for quantitative analysis of Ti in $TiO_{2}$ sample. $TiO_{2}$ powder sample was mixed with polyvinyl alcohol and formed into pellets. An Nd:YAG pulsed laser at a wavelength of 1064 nm was focused onto the sample to generate plasma. The spectrum of plasma was recorded using spectrophotometer then compared to NIST spectral line to determine energy levels and other parameters. The value of plasma temperature obtained using Boltzmann plot is 8127.29 K and electron density from calculation is $2.49×10^{16}$ $cm^{-3}$. Finally, the concentration of Ti in $TiO_{2}$ sample from this study is 97% that is in proximity with the sample certificate. |
| Related Links | http://iopscience.iop.org/article/10.1088/1742-6596/985/1/012010/pdf |
| ISSN | 17426588 |
| e-ISSN | 17426596 |
| DOI | 10.1088/1742-6596/985/1/012010 |
| Journal | Journal of Physics: Conference Series |
| Issue Number | 1 |
| Volume Number | 985 |
| Language | English |
| Publisher | IOP Publishing |
| Publisher Date | 2018-03-19 |
| Access Restriction | Open |
| Subject Keyword | Journal: Journal of Physics: Conference Series |
| Content Type | Text |
| Resource Type | Article |
| Subject | Physics and Astronomy |