NDLI: Acid-catalyzed Rearrangement of O-Menthyl Methylthiocarbamate

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Acid-catalyzed Rearrangement of O-Menthyl Methylthiocarbamate

Content Provider	Scilit
Author	Kinoshita, Yoshiro Misaka, Michinori Kubota, Shuhei Ishikawa, Hisao
Copyright Year	1977
Description	Journal: Bioscience, Biotechnology, and Biochemistry O-Menthyl methylthiocarbamate was treated with boron trifluoride etherate producing S-menthyl methylthiocarbamate (4%) and S-p-menthan-8-yl methylthiocarbamate (56%). On the basis of this result, it was concluded that the rearrangement of secondary O-alkyl thiocarbamates proceeds by $S_{N}$1 mechanism whereas primary O-alkyl thiocarbamates rearrange by $S_{N}$2.
Related Links	https://www.tandfonline.com/doi/pdf/10.1080/00021369.1977.10862865?needAccess=true
Ending Page	2360
Page Count	4
Starting Page	2357
ISSN	09168451
e-ISSN	13476947
DOI	10.1080/00021369.1977.10862865
Journal	Bioscience, Biotechnology, and Biochemistry
Issue Number	12
Volume Number	41
Language	English
Publisher	Informa UK Limited
Publisher Date	1977-12-01
Access Restriction	Open
Subject Keyword	Journal: Bioscience, Biotechnology, and Biochemistry Organic Chemistry Boron Trifluoride Sn1 Mechanism Acid Catalyzed Alkyl Thiocarbamates Methylthiocarbamate Thiocarbamates Proceeds
Content Type	Text
Subject	Organic Chemistry Medicine Analytical Chemistry Molecular Biology Biochemistry Applied Microbiology and Biotechnology Biotechnology

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