NDLI: Enhanced-Fluidity Liquid Mixtures: Fundamental Properties and Chromatography

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Enhanced-Fluidity Liquid Mixtures: Fundamental Properties and Chromatography

Content Provider	Scilit
Copyright Year	2007
Description	An important goal in numerous chromatographic applications is to improve the separation power, P (Equation 9.1) or the speed of the separation [1]:P(s−1) = dN dt. (9.1)This improvement is especially important in routine analyses and in largescale evaluation studies, such as the combinatorial characterization of drug candidates. High temperature (HT), HT high-performance liquid chromatography (HT-HPLC), and supercritical fluid chromatography (SFC) are common methods considered when separation speed is essential due the increased mass transport and decreased viscosity obtained with both techniques [2]. However, both SFC and HT-HPLC have deficiencies that limit their applicability [2,3]. For example, carbon dioxide, the most commonly-used solvent in SFC, has limited solvent strength even with the addition of small quantities of polar modifiers. The increased temperatures used in HT-HPLC can cause on-column reactions of the analytes [4]. Herein, we focus on enhanced-fluidity liquid chromatography (EFLC) that shares many of the positive attributes of each of these techniques without the negative attributes. Book Name: Advances in Chromatography, Volume 46
Related Links	https://api.taylorfrancis.com/content/chapters/edit/download?identifierName=doi&identifierValue=10.1201/9781420060263-11&type=chapterpdf
Ending Page	458
Page Count	28
Starting Page	431
DOI	10.1201/9781420060263-11
Language	English
Publisher	Informa UK Limited
Publisher Date	2007-11-05
Access Restriction	Open
Subject Keyword	Book Name: Advances in Chromatography, Volume 46 Analytical Chemistry Chromatography Enhanced Fluidity Liquid
Content Type	Text
Resource Type	Chapter

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