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Optical Ligand to Ligand Charge Transfer of Metal Complexes Including Ligand-Based Mixed-Valence Systems
| Content Provider | Scilit |
|---|---|
| Author | Vogler, Arnd Kunkely, Horst |
| Copyright Year | 1990 |
| Description | The electronic spectra of metal complexes which contain a reducing and an oxidizing ligand $(L_{red}–M–L_{ox}$) are characterized by ligand to ligand charge transfer (LLCT) absorptions. A specific form of $L_{red}–M–L_{ox}$ complexes are ligand-based mixed-valence (LBMV) compounds which contain the same ligand in two different redox states. In this case the ligand-ligand interaction may lead to a partial or even complete electronic delocalization between the reduced and oxidized form of the ligands. As a consequence, the “LLCT” transition loses its CT character since it takes place between delocalized orbitals. |
| Related Links | https://epub.uni-regensburg.de/13504/1/vogler99.pdf https://core.ac.uk/download/pdf/11543882.pdf |
| Ending Page | 220 |
| Page Count | 20 |
| Starting Page | 201 |
| ISSN | 02603594 |
| e-ISSN | 15489574 |
| DOI | 10.1080/02603599008035810 |
| Journal | Comments on Inorganic Chemistry |
| Issue Number | 3-4 |
| Volume Number | 9 |
| Language | English |
| Publisher | Informa UK Limited |
| Publisher Date | 1990-01-01 |
| Access Restriction | Open |
| Subject Keyword | Inorganic Chemistry Mixed-valence Complexes Electronic Spectra Optical Electron Transfer |
| Content Type | Text |
| Resource Type | Article |
| Subject | Inorganic Chemistry |
