NDLI: Nucleophilic Opening of an Epoxide by a Masked Glycine Anion Equivalent: A Route to C-Glycosyl Amino Acids

Content Provider	Scilit
Author	Gravier-Pelletier, Christine Gayral, Maud Frlan, Rok Mravljak, Janez
Copyright Year	2016
Description	An efficient method has been developed for the synthesis of C-glycosyl amino acids through a tandem nucleophilic opening–cyclization of an l-ido-bisepoxide with the anion of Schöllkopf’s bislactim. A masked amine was introduced at the $CH_{2}C_{1}$-position of the resulting compound. The products are enantiopure polyfunctionalized intermediates, suitable for further synthesis of antibacterial compounds.
Related Links	http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0035-1561987.pdf
Ending Page	1556
Page Count	6
Starting Page	1551
ISSN	09365214
e-ISSN	14372096
DOI	10.1055/s-0035-1561987
Journal	Synlett
Issue Number	10
Volume Number	27
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2016-03-18
Access Restriction	Open
Subject Keyword	Organic Chemistry Glycosyl Amino Acids Medicinal Chemistry
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry

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Nucleophilic Opening of an Epoxide by a Masked Glycine Anion Equivalent: A Route to C-Glycosyl Amino Acids