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Carbonylative Suzuki–Miyaura Coupling Reactions of Aryl Iodides with Readily Available Polymer-Immobilized Palladium Nanoparticles
| Content Provider | Scilit |
|---|---|
| Author | Yasukawa, Tomohiro Kobayashi, Shu Zhu, Zhiyuan Yamashita, Yasuhiro |
| Copyright Year | 2020 |
| Description | Polysilane/alumina-supported palladium nanoparticle catalyzed carbonylative Suzuki–Miyaura coupling reactions under ligand-free conditions have been developed to synthesize diaryl ketones. High yields and selectivities were achieved even with low catalyst loading under atmospheric pressure of CO gas. A variety of aryl iodides and arylboronic acids could be utilized to afford the diaryl ketones in excellent yields. Moreover, the ligand-free immobilized palladium nanoparticles could be recovered by simple filtration and the catalytic activity could be maintained for several runs. |
| Related Links | http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0040-1707243.pdf |
| ISSN | 09365214 |
| e-ISSN | 14372096 |
| DOI | 10.1055/s-0040-1707243 |
| Journal | Synlett |
| Language | English |
| Publisher | Georg Thieme Verlag KG |
| Publisher Date | 2020-08-26 |
| Access Restriction | Open |
| Subject Keyword | Organic Chemistry Carbonylative Suzuki–miyaura Coupling Heterogeneous Catalyst Palladium Catalyst |
| Content Type | Text |
| Resource Type | Article |
| Subject | Organic Chemistry |
