NDLI: Biomimetic Oxidation of Alcohols Catalyzed by TEMPO-Functionalized Polyethylene Glycol and Copper(I) Chloride in Compressed Carbon Dioxide

Content Provider	Scilit
Author	He, Liang-Nian Miao, Cheng-Xia Wang, Jin-Quan Gao, Jian
Copyright Year	2009
Description	Recyclable TEMPO-functionalized polyethylene glycol $[PEG_{6000}-(TEMPO)_{2}$] in combination with cuprous chloride were developed for biomimetic oxidation of a series of benzylic, allylic, heterocyclic alcohols, and 2-phenylethanol into the corresponding aldehydes or ketones in high selectivity and in moderate to high conversion in compressed $CO_{2}$, which enhanced the catalytic activity as well as improved the selectivity.
Related Links	http://pdfs.semanticscholar.org/5ade/528cacb4526519c0c862ef67ec1b060cb0fc.pdf http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0029-1218375.pdf
Ending Page	3294
Page Count	4
Starting Page	3291
ISSN	09365214
e-ISSN	14372096
DOI	10.1055/s-0029-1218375
Journal	Synlett
Issue Number	20
Volume Number	2009
Language	English
Publisher	Georg Thieme Verlag KG
Publisher Date	2009-11-18
Access Restriction	Open
Subject Keyword	Journal: Synlett Organic Chemistry Alcohol Oxidation Carbon Dioxide Copper(i) Chloride
Content Type	Text
Resource Type	Article
Subject	Organic Chemistry

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Biomimetic Oxidation of Alcohols Catalyzed by TEMPO-Functionalized Polyethylene Glycol and Copper(I) Chloride in Compressed Carbon Dioxide