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Palladium-Catalyzed Desulfurative Hiyama Coupling of Thioureas to Achieve Amides via Selective C–N Bond Cleavage
| Content Provider | Scilit |
|---|---|
| Author | Zeng, Zhuo He, Zhanyu Yan, Chu Zhang, Mei Irfan, Majeed Wang, Zijia |
| Copyright Year | 2021 |
| Description | Palladium-catalyzed Hiyama coupling of active thioureas via selective C–N bond cleavage is reported. Notably, the new approach employed active thioureas as coupling partners in the presence of arylsilanes to give amides in good yield. Further, this strategy, which utilized $CuF_{2}$ as a key oxidant and activator, afforded various amide products under mild conditions and an easy to handle procedure without extra base. Received: 03 August 2021 Accepted after revision: 13 September 2021 Publication Date: 14 October 2021 (online) © 2021. Thieme. All rights reserved Georg Thieme Verlag KG Rüdigerstraße 14, 70469 Stuttgart, Germany |
| Related Links | http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0040-1720907.pdf |
| Ending Page | 710 |
| Page Count | 6 |
| Starting Page | 705 |
| ISSN | 00397881 |
| e-ISSN | 1437210X |
| DOI | 10.1055/s-0040-1720907 |
| Journal | Synthesis |
| Issue Number | 03 |
| Volume Number | 54 |
| Language | English |
| Publisher | Georg Thieme Verlag KG |
| Publisher Date | 2021-10-14 |
| Access Restriction | Open |
| Subject Keyword | Journal: Synthesis Desulfurative Hiyama Coupling Cuf2 Activator Selective C–n Bond Cleavage |
| Content Type | Text |
| Resource Type | Article |
| Subject | Organic Chemistry Catalysis |
