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Recent Advances in Ring-Opening Polymerization of O-Carboxyanhydrides
| Content Provider | Scilit |
|---|---|
| Author | Xie, Linghai Tong, Rong Feng, Quanyou Zhong, Yongliang |
| Copyright Year | 2017 |
| Description | Poly(α-hydroxy acids) are important biodegradable polymers with wide applications. Recently O-carboxyanhydrides (OCAs) have emerged as promising monomer equivalents of lactides to synthesize poly(α-hydroxy acids). We will highlight recent advances in controlled ring-opening polymerization of OCAs catalyzed by organocatalysts, enzymes, or organometallic complexes.1 Introduction2 Organocatalysts for O-Carboxyanhydride Polymerization2.1 Synthesis of O-Carboxyanhydride Monomers2.2 Ring-Opening Polymerization of O-Carboxyanhydrides Catalyzed by 4-Dimethylaminopyridine2.3 Epimerization in the Ring-Opening Polymerization of O-Carboxyanhydrides Catalyzed by the Pyridine Base2.4 N-Heterocyclic Carbenes for Ring-Opening Polymerization of O-Carboxyanhydrides3 Enzymes for O-Carboxyanhydride Polymerization4 Organometallic Catalysts for O-Carboxyanhydride Polymerization4.1 Early Efforts4.2 Ring-Opening Polymerization Catalyzed by Zn Complexes4.3 Photoredox Ring-Opening Polymerization Catalyzed by Zn/Ni Complexes5 Conclusion and Perspective |
| Related Links | http://www.thieme-connect.de/products/ejournals/pdf/10.1055/s-0036-1590841.pdf |
| Ending Page | 1866 |
| Page Count | 10 |
| Starting Page | 1857 |
| ISSN | 09365214 |
| e-ISSN | 14372096 |
| DOI | 10.1055/s-0036-1590841 |
| Journal | Synlett |
| Issue Number | 15 |
| Volume Number | 28 |
| Language | English |
| Publisher | Georg Thieme Verlag KG |
| Publisher Date | 2017-08-03 |
| Access Restriction | Open |
| Subject Keyword | O-carboxyanhydrides Ring-opening Polymerization Poly(α-hydroxy Acid) |
| Content Type | Text |
| Resource Type | Article |
| Subject | Organic Chemistry |